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Paul Voyles with graduate student Jason Maldonis
March 19, 2018

Liquid-to-glass transition process gains clarity

Written By: Renee Meiller

For millennia, people have used molten sand and other ingredients to create a vast array of traditional glass products, including beads, vessels, lenses and windows.

These days, metallic glasses—made entirely of metal atoms—are being developed for biomedical applications such as extra-sharp surgical needles, stents, artificial joints or implants because various alloys can be ultra-hard, extra strong, very smooth and resistant to corrosion.

However, while a combination of trial and error and scientific research have helped refine glassmaking processes over time, at the atomic level, controlling the creation of metallic glasses remains an inexact endeavor informed largely by long experience and intuition.

“Our job,” says Paul Voyles, “is to build fundamental understanding by adding more data.”

The Beckwith-Bascom Professor in materials science and engineering at the University of Wisconsin-Madison, Voyles and collaborators on campus and at Yale University have made significant experimental strides in understanding how, when and where the constantly moving atoms in molten metal “lock” into place as the material transitions from liquid to solid glass.

They described what they observed about how those atoms rearrange at different temperatures over time in the March 19, 2018, edition of the journal Nature Communications.

It’s knowledge that can add much-needed experimental clarity to several competing theories about how that process, called the glass transition, occurs. Ultimately it also could help reduce time and costs associated with developing new metallic glass materials and provide manufacturers greater insight into process design.

One processing challenge is that as it transitions from molten liquid to solid, a metal’s tendency is to form orderly, regularly repeating atomic structures called crystals. In contrast, glass materials have a highly disordered atomic structure. And while making a high-performance metallic glass sounds as simple as preventing metal atoms from forming crystals as the material cools, in reality, it relies somewhat on the luck of the draw.

“The process that makes a glass and the process that makes a crystal compete with each other, and the one that wins—the one that happens at a faster rate—determines the final product,” says Voyles.

In a liquid, all of the atoms are moving past each other at all times, he says. As a molten metal cools and begins its transition to a solid, its atoms slow down and eventually stop moving.

It’s a complicated atomic-level dance that scientists are still unraveling. Drawing on their expertise in electron microscopy and data analysis, Voyles and his collaborators have measured how long it takes, on average, for an atom to gain or lose adjacent atoms as its environment fluctuates in the molten liquid. “An atom is surrounded by a bunch of other atoms,” he says. “At really high temperatures, they bounce around and every picosecond, they have a new set of neighbors. As the temperature decreases, they stick with their neighbors longer and longer until they stick permanently.”

At high temperatures, the atoms all move fast. Then, as the liquid cools, they move more slowly; a simple description might be that all of the atoms slow down together, at the same rate, until they stop moving and the material becomes a solid glass. “We have now demonstrated experimentally that is not what happens,” says Voyles.

Rather, he says, his team’s experiments confirmed that the time it takes for atoms to lock into place varies widely—by at least an order of magnitude—from place to place inside the same liquid. “Some nanometer-sized regions get ‘sticky’ first and hold on to their neighbors for a very long time, whereas between the sticky bits are bits that are moving much more quickly,” he says. “They continue to fluctuate 10 times faster than in the slow parts and then everything gets slower, but the sticky parts also get bigger until the sticky parts ‘win’ and the material becomes a solid.”

Now, he and his collaborators are working to understand how the atomic arrangements differ between the slow and fast parts. “That’s the next big missing piece of the puzzle,” he says.

The advance provides valuable information about the fundamental process through which every glass material—from window glass to plastic bottles to pharmaceutical preparations and many others—transitions from liquid to solid, says Voyles. “This is really basic science,” he says. “But the ultimate potential impact for applications is if we really understand how this works at the atomic level, that gives us the opportunity to build in control that lets us make glasses out of what we want instead of only getting glasses when we get lucky.”

Funding from the National Science Foundation (Nos. DMR-1506564 and DMR-1121288) and from the U.S. Department of Energy Office of Basic Energy Sciences (No. DE SC0004889) supported the research. Other authors on the paper include Pei Zhang, Jason Maldonis of UW-Madison and Ze Liu and Jan Schroers of Yale University.